Orpiment, also known as yellow arsenic blende, is a deep-colored, orange-yellow arsenic sulfide mineral with formula As2S3. It is found in volcanic fumaroles, low-temperature hydrothermal veins, and hot springs and may be formed through sublimation. Orpiment takes its name from the Latin auripigmentum (aurum, "gold" + pigmentum, "pigment"), due to its deep-yellow color. Orpiment once was widely used in artworks, medicine, and other applications. Because of its toxicity and instability, its usage has declined.

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